I would double check your pop server port settings and smtp port settings. Depending on who you use, you may need to specify specific port numbers. For example, gmail requires a certain port numbers specified.
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To add BCC field to view in Sent Folders in Oulook 2010:
1. Click on "Sent Folders"
2. Select "View" from Ribbon Menu at the top of Outlook
3. Click "Add Columns"
4. Select "Address Fields" in the drop down menu
5. Select "Bcc"
To clarify, do you mean you have a setting to forward?
firstname.lastname@example.org to email@example.com
If this is the case and you will not see the messages in your sent folder b/c the forward is usually set from the server. You would normally login to the server options and set that is in...
The program is probably trying to remove a data file PST in a location the location that does not exist anymore.
I would create a temp PST with the exact name of that data file and place it in the location as pointed in outlook.
Then, attempt to remove that data file from outlook.