Outlook 10 - Default email account not automatically used for new emails

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Hi - I have multiple email accounts (mix of IMAP and POP) which I have set up in Outlook 10. My main email account (IMAP) is set as the default email account. But when I want to send a new email it is not the default account which is used but one of my other accounts (always the same/the first POP account in my account list).

I tried to change the default settings and set it back to my main account but this doesn't help. Is this a known bug? Do I do something wrong (it used to work fine with old Outlook versions)? Has anybody a solution?

Thanks a lot,


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